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2023

# First Authors

(54) Mechanistic Insights into ZIF-8 Encapsulation of Atom-Precise Pt(M) Carbonyl Clusters

K. L. Kollmannsberger, Poonam, C. Cesari, R. Khare, T. Kratky, M. Boniface, O. Tomanec, J. Michalička, E. Mosconi, A. Gagliardi, S. Günther, W. Kaiser, T. Lunkenbein, S. Zacchini, J. Warnan*, R. A. Fischer*, Chem. Mater. 2023. 10.1021/acs.chemmater.3c00807

(53) Structure–Activity Relationships in Ni- Carboxylate-Type Metal–Organic Frameworks’ Metamorphosis for the Oxygen Evolution Reaction.

X. Ma, D. J. Zheng, S. Hou, S. Mukherjee, R. Khare, G. Gao, Q. Ai, B. Garlyyev, W. Li, M. Koch, J. Mink, Y. Shao-Horn, J. Warnan*, A. S. Bandarenka*, R. A. Fischer*, ACS Catal. 2023, 13, 7587-7596.

(52) Defect Engineering in MIL-125-(Ti)-NH2 for Enhanced Photocatalytic H2 Generation

L. Pukdeejorhor, S. Wannapaiboon, J. Berger, K. Rodewald, S. Thongratkaew, S. Impeng, J. Warnan*, S. Bureekaew, R. A. Fischer*, J. Mater. Chem. A, 2023,11, 9143-9151

Frontispiece - anie.202183361_page-0001.jpg
Mol. Syst. Des. Eng., 2021,6, 876-882.jpg

(51) Photocatalytic CO2-to-syngas Evolution with Molecular Catalyst Metal-organic Framework Nanozymes.

P. M. Stanley, A. Y. Su, V. Ramm, P. Fink, C. Kimna, O. Lieleg, M. Elsner, J. A. Lercher, B. Rieger, J. Warnan,* R. A. Fischer*, Adv. Mater., 2023, 35, 2207380

(50) Decoupled Solar Energy Storage and Dark Photocatalysis in a 3D Metal-organic Framework.

P. M. Stanley, F. Sixt, J. Warnan*, Adv. Mater., 2023, 35, 2207280.

2022

(49) Merging molecular catalysts and metal–organic frameworks for photocatalytic fuel production.

P. M. Stanley, J. Haimerl, N. B. Shustova, R. A. Fischer, J. Warnan,* Nature Chem. 2022, 14, 1342-1356.

(48) Topology- and wavelength-governed CO2 reduction photocatalysis in molecular catalyst-metal-organic framework assemblies.

P. M. Stanley,# K. Hemmer,# M. Hegelmann, A. Schulz, M. Park, M. Elsner, M. Cokoja, J. Warnan*, Chem. Sci., 2022, 13, 12164-12174.

(47) Dual In-situ Laser Techniques Underpin the Role of Cations in Impacting Electrocatalysts.

S. Hou, L. Xu, X. Ding, R. M. Kluge, T. K. Sarpey, R. W. Haid, B. Garlyyev, S. Mukherjee, J. Warnan, M. Koch, S. Zhang, W. Li, A. S. Bandarenka, R. A. Fischer, Angew. Chem. Int. Ed. 2022, 61, e202201610

(46) Photoelectrochemical hybrid cell for unbiased CO2 reduction coupled to alcohol oxidation.

D. Antón-García, E. Edwardes Moore, M. A. Bajada, A. Eisenschmidt, A. R. Oliveira, I. A. C. Pereira, J. Warnan*, E. Reisner*, Nat. Synthesis 2022, 1, 77-86.

2021

(45) Introducing Benzene-1,3,5-tri(dithiocarboxylate) as a Multidentate Linker in Coordination Chemistry.

M. Aust, A. J. Herold, L. Niederegger, C. Schneider, D. C. Mayer, M. Drees, J. Warnan*, A. Pöthig*, R. A. Fischer*, Inorg. Chem. 2021, 60, 19242–19252

(44) From Phosphine-Stabilised towards Naked Au8 Clusters through ZIF-8 Encapsulation.

K. L. Kollmannsberger, K. Weger, T. Kratky, S. Guenther, O. Tomanec, J. Warnan*, R. A. Fischer*, Mol. Syst. Des. Eng., 2021, 6, 876-882

(42) Host-Guest Interactions in Metal-Organic Framework Isoreticular Series for Molecular Photocatalytic CO2 Reduction

P. M. Stanley, J. Haimerl, C. Thomas, A. Urstoeger, M. Schuster, N. B. Shustova, A. Casini, B. Rieger, J. Warnan*, R. A. Fischer*, Angew. Chem. Int. Ed. 2021, 60, 17854–17860.

(41) Understanding entrapped molecular photosystem and metal-organic framework synergy for improved solar fuel production.

P. M. Stanley, M. Parkulab, B. Rieger, J. Warnan*, R. A. Fischer*, Faraday Discuss., 2021, 231, 281-297

(40) Electrocatalytic and Solar-Driven Reduction of Aqueous CO2 with Molecular Cobalt Phthalocyanine–Metal Oxide Hybrid Materials.

S. Roy, M. Miller, J. Warnan, J. J. Leung, C. D. Sahm, E. Reisner, ACS Catal. 2021, 11, 1868-1876.

(39) Entrapped Molecular Photocatalyst and Photosensitizer in Metal–Organic Framework Nanoreactors for Enhanced Solar CO2 Reduction.

P. M. Stanley, C. Thomas, E. Thyrhaug, A. Urstoeger, M. Schuster, J. Hauer, B. Rieger, J. Warnan*, R. A. Fischer*, ACS Catal. 2021, 11, 871-882.

(38) Charge Accumulation Kinetics in Multi-Redox Molecular Catalysts Immobilised on TiO2.

C. Bozal-Ginesta, C. A. Mesa, A. Eisenschmidt, L. Francàs, R. Shankar, D. Antón-García, J. Warnan, J. Willkomm, A. Reynal, E. Reisner, J. Durrant, Chem. Sci. 2021, 12, 946-959.

(37) Porphyrin based metal-organic framework films: nucleation and growth.

Z. Zhou, S. Mukherjee, J. Warnan, W.-J. Li, S. Wannapaiboon, S. Hou, K. Rodewald, B. Rieger, P. G. Weidler, C. Wöll, R. A. Fischer, J. Mater. Chem. A 2020, 8, 25941-25950

2020

(36) A diketopyrrolopyrrole dye-based dyad on a porous TiO2 photoanode for solar-driven water oxidation.

D. Antón-García, J. Warnan, E. Reisner, Chem. Sci. 2020, 11, 12769-12776.

(35) Molecularly engineered photocatalyst sheet for scalable solar formate production from carbon dioxide and water.

Q. Wang, J. Warnan, S. Rodríguez-Jiménez, J. J. Leung, S. Kalathil, V. Andrei, K. Domen, E. Reisner, Nature Energy 2020, 5, 703-710.

(34) Synthetic organic design for solar fuel systems.

J. Warnan*, E. Reisner*, Angew. Chem. Int. Ed. 2020, 59, 17344-17354.

(33) A Precious-Metal-Free Hybrid Electrolyzer for Alcohol Oxidation Coupled to CO2-to-Syngas Conversion.

M. A. Bajada#, S. Roy#, J. Warnan#, K. Abdiaziz, A. Wagner, M. M. Roessler, E. Reisner, Angew. Chem. Int. Ed. 2020, 59, 15633-15641.

2019

(32) Inverse Opal CuCrO2 Photocathodes for H2 Production using Organic Dyes and a Molecular Ni Catalyst.

C. E. Creissen, J. Warnan, D. Antón-García, Y. Farré, F. Odobel, E. Reisner, ACS Catal. 2019, 9, 9530-9538.

(31) Rational Design of Polymers for Selective CO2 Reduction Catalysis.

J. J. Leung#, J. A. Vigil#, J. Warnan#, E. Edwardes Moore, E. Reisner, Angew. Chem. Int. Ed. 2019, 58, 7697-7701.

(30) Solar-Driven Reduction of Aqueous CO2 with a Co bis(terpyridine)-based Photocathode.

J. J. Leung#, J. Warnan#, K. H. Ly, N. Heidary, D. H. Nam, M. F. Kuehnel, E. Reisner, Nature Catalysis 2019, 2, 354-365.

(29) Interfacing Formate Dehydrogenase with Metal Oxides for Reversible Electrocatalysis or Solar-Driven Reduction of Carbon Dioxide.

M. Miller, W. E. Robinson, A. R. Oliveira, N. Heidary, N. Kornienko, J. Warnan, I. A. C. Pereira, E. Reisner, Angew. Chem. Int. Ed. 2019, 58, 4601-4605.

(28) Electro- and Solar-Driven Fuel Synthesis with First Row Transition Metal Complexes.

K. E. Dalle#, J. Warnan#, J. J. Leung, B. Reuillard, I. S. Karmel, E. Reisner, Chem. Rev. 2019, 119, 2752-2875.

(27) Solar Electricity and Fuel Production with Perylene Monoimide Dye-sensitised TiO2 in Water.

J. Warnan, J. Willkomm, Y. Farré, Y. Pellegrin, M. Boujtita, F. Odobel, E. Reisner, Chem. Sci. 2019, 10, 2758-2766.

2018

(26) Photoreduction of CO2 with a formate dehydrogenase driven by photosystem II using a semi-artificial Z-scheme architecture.

K. P. Sokol, W. E. Robinson, A. R. Oliveira, J. Warnan, M. M. Nowaczyk, A. Ruff, I. A. C. Pereira, E. Reisner, J. Am. Chem. Soc. 2018, 140, 16418-16422.

(25) Bias-free photoelectrochemical water splitting with photosystem II on a dye-sensitised photoanode wired to hydrogenase.

K. P. Sokol, W. E. Robinson, J. Warnan, N. Kornienko, M. M. Nowaczyk, A. Ruff, J. Z. Zhang, E. Reisner, Nature Energy 2018, 3, 944-951.

(24) Redox-Driven Porphyrin based Systems for New Luminescent Molecular Switches.

L. Norel, C. Tourbillon, J. Warnan, J.-F. Audibert, Y. Pellegrin, F. Miomandre, F. Odobel, S. Rigaut, Dalton Trans. 2018, 47, 8364-8374.

(23) Solar H2 generation in water with a CuCrO2 photocathode modified with an organic dye and molecular Ni catalyst.

C. E. Creissen, J. Warnan, E. Reisner, Chem. Sci. 2018, 9, 1439-1447.

2017

(22) Photoelectrocatalytic H2 evolution in water with molecular catalysts immobilised on p-Si via a stabilising mesoporous TiO2 interlayer.

J. J. Leung#, J. Warnan#, N. Dong Heon, J. Z. Zhang, J. Willkomm, E. Reisner, Chem. Sci. 2017, 8, 5172-5180.

(21) Solar H2 evolution in water with modified diketopyrrolopyrrole dyes immobilised on molecular Co and Ni catalyst-TiO2 hybrids.

J. Warnan#, J. Willkomm#, J. N. Ng, R. Godin, S. Prantl, J. R. Durrant, E. Reisner, Chem. Sci. 2017, 8, 3070-3079.

2016

(20) Metal-encapsulated organolead halide perovskite photocathode for solar-driven hydrogen evolution in water.

M. Crespo-Quesada, L. M. Pazos-Outón, J. Warnan, M. F. Kuehnel, R. H. Friend, E. Reisner, Nat. Commun. 2016, 7, 12555.

(19) Trans-disubstituted benzodiazaporphyrin: A promising hybrid dye between porphyrin and phthalocyanine for application in dye-sensitized solar cells.

D. S. Andrianov, Y. Farre, K. J. Chen, J. Warnan, A. Planchat, D. Jacquemin, A. V. Cheprakov, F. Odobel, J. Photochem. Photobiol. A: Chem. 2016, 330, 186-194.

(18) A Poly(cobaloxime)/Carbon Nanotube Electrode: Freestanding Buckypaper with Polymer-Enhanced H2-Evolution Performance.

B. Reuillard#, J. Warnan#, J. J. Leung, D. W. Wakerley, E. Reisner, Angew. Chem. Int. Ed. 2016, 55, 3952-3957.

2015

(17) Molecular Packing and Arrangement Govern the Photo-Oxidative Stability of Organic Photovoltaic Materials.

W. R. Mateker, T. Heumueller, R. Cheacharoen, I. T. Sachs-Quintana, M. D. McGehee, J. Warnan, P. M. Beaujuge, X. Liu, G. C. Bazan, Chem. Mater. 2015, 27, 6345-6353.

(16) Amplification of Light Collection in Solid-State Dye-Sensitized Solar Cells via Antenna Effect with Supramolecular Assembly.

B. L. M'Sabah, M. Boucharef, J. Warnan, Y. Pellegrin, E. Blart, B. Lucas, F. Odobel, J. Boucle, Phys. Chem. Chem. Phys. 2015, 17, 9910-9918.

2014

(15) Dependence of Crystallite Formation and Preferential Backbone Orientations on the Side Chain Pattern in PBDTTPD Polymers.

A. El Labban, J. Warnan, C. Cabanetos, O. Ratel, C. Tassone, M. F. Toney, P. M. Beaujuge, ACS Appl. Mater. Interfaces 2014, 6, 19477-19481.

(14) Ordering Effects in Benzo[1,2-b:4,5-b′]difuran-Thieno[3,4-c]pyrrole-4,6-dione Polymers with >7% Solar Cell.

J. Warnan, C. Cabanetos, A. El Labban, M. R. Hansen, C. Tassone, M. F. Toney, P. M. Beaujuge, Adv. Mater. 2014, 26, 4357-4362.

(13) Electron-Deficient N-Alkyloyl Derivatives of Thieno[3,4-c]pyrrole-4,6-dione Yield Efficient Polymer Solar Cells with Open-Circuit Voltages >1V.

J. Warnan, C. Cabanetos, R. Bude, A. El Labban, L. Li, P. M. Beaujuge, Chem. Mater. 2014, 26, 2829-2835.

(12) Ring Substituents Mediate the Morphology of PBDTTPD-PCBM Bulk-Heterojunction Solar Cells.

J. Warnan, A. El Labban, C. Cabanetos, E. T. Hoke, P. K. Shukla, C. Risko, J.-L. Bredas, M. D. McGehee, P. M. Beaujuge, Chem. Mater. 2014, 26, 2299-2306.

(11) Acetylacetone Anchoring Group for NiO-Based Dye-Sensitized Solar Cell.

J. Warnan, Y. Pellegrin, E. Blart, L. Zhang, A. Brown, L. Hammarstrom, D. Jacquemin, F. Odobel, Dyes Pigm. 2014, 105, 174-179.

(10) Multi-chromophoric sensitizers based on squaraine for NiO based dye sensitized solar cells.

J. Warnan, J. Gardner, L. Le Pleux, J. Petersson, Y. Pellegrin, E. Blart, L. Hammarstrom, F. Odobel, J. Phys. Chem. C 2014, 118, 103-113.

2013

(9) Diketopyrrolopyrrole derivatives for efficient NiO-based dye-sensitized solar cells.

L. Favereau, J. Warnan, Y. Pellegrin, E. Blart, M. Boujtita, D. Jacquemin, F. Odobel, Chem. Commun. 2013, 49, 8018-8020.

(8) Diketopyrrolopyrrole-zinc porphyrin, a tuned panchromatic association for dye-sensitized solar cells.

L. Favereau#, J. Warnan#, F. B. Anne, Y. Pellegrin, E. Blart, D. Jacquemin, F. Odobel, J. Mater. Chem. A 2013, 1, 7572-7575.

(7) Ruthenium Sensitizer Functionalized by Acetylacetone Anchoring Groups for Dye-Sensitized Solar Cell.

J. Warnan, V.-M. Guerin, F. B. Anne, Y. Pellegrin, E. Blart, D. Jacquemin, T. Pauporte, F. Odobel, J. Phys. Chem. C 2013, 117, 8652-8660.

(6) Bio-inspired artificial light-harvesting antennas for enhancement of solar energy capture in dye-sensitized solar cells.

F. Odobel, Y. Pellegrin, J. Warnan, Energy Environ. Sci. 2013, 6, 2041-2052.

2012

(5) Diketopyrrolopyrrole-porphyrin conjugates as broadly absorbing sensitizers for dye-sensitized solar cells.

J. Warnan, L. Favereau, F. Meslin, M. Severac, E. Blart, Y. Pellegrin, D. Jacquemin, F. Odobel, ChemSusChem 2012, 5, 1568-1577.

(4) Supramolecular light harvesting antennas to enhance absorption cross-section in dye-sensitized solar cells.

J. Warnan, Y. Pellegrin, E. Blart, F. Odobel, Chem. Commun. 2012, 48, 675-677.

2011

(3) A compact diketopyrrolopyrrole dye as efficient sensitizer in titanium dioxide dye-sensitized solar cells.

J. Warnan, L. Favereau, Y. Pellegrin, E. Blart, D. Jacquemin, F. Odobel, J. Photochem. Photobiol. A: Chem. 2011, 226, 9-15.

(2) Panchromatic Trichromophoric Sensitizer for Dye-Sensitized Solar Cells Using Antenna Effect.

J. Warnan, F. Buchet, Y. Pellegrin, E. Blart, F. Odobel, Org. Lett. 2011, 13, 3944-3947.

(1) Application of Poly(3-hexylthiophene) Functionalized with an Anchoring Group in Dye-sensitized Solar Cells.

J. Warnan, Y. Pellegrin, E. Blart, F. Odobel, W. Zhang, B. Liu, V. J. Babu, S. Ramakrishna, Macromol. Rapid Commun. 2011, 32, 1190-1194.

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